Publications by David M. Eichhorn

47. Zimmerman, J.R.; Smucker, B.W.; Dain, R.P.; VanStipdonk, M.J.; Eichhorn, D.M.; “Tridentate N2S ligand from 2,2’-dithiodibenzaldehyde and N,N-dimethylethylenediamine: Synthesis, structure, and characterization of a Ni(II) complex with relevance to Ni Superoxide Dismutase”; Inorg. Chim. Acta 2011,373 54-61. DOI 10.1016/j.ica.2011.03.052

46. Andra, K.K.; Bullinger, J.C.; Bann, J.G.; Eichhorn, D.M.; 2-Fluoro-L-Histidine; Acta Cryst. 2010, E66, o2713. DOI 10.1107/S1600536810038663

45. Dou, D.; He, G.; Lai, Z.; Wei, L.; Alliston, K.R.; Lushington, G.H.; Eichhorn, D.M.; Groutas, W.C.; “Utilization of the 1,2,3,5-thiatriazolidin-3-one 1,1-Dioxide Scaffold in the Design of Potential Inhibitors of Human Leukocyte Proteinase 3“; Bioorg. Med. Chem. 2010, 18, 1093-1102. DOI 10.1016/j.bmc.2009.12.057

44. Eichhorn, D.M.; “Analysis of ‘Janus Scorpionates: Supramolecular Tectons for the Directed Assembly of Hard–Soft Alkali Metallopolymer Chains’ and ‘A Second-Generation Janus Scorpionate Ligand: Controlling Coordination Modes in Iron(II) Complexes’”; Chemtracts Organic Chemistry 2009, 22, 135-140.

43. Bullinger, J.C.; Eichhorn, D.M.; “Cyanoscorpionates: Co(II), Mn(II), and Ni(II) Complexes Coordinated Only Through the Cyano Group”; Inorg. Chim. Acta, 2009, 362, 4510-4516. DOI 10.1016/j.ica.2009.05.012

42. Panja, A.; Eichhorn, D.M.; “Synthesis and Characterization of Tetrahedrally and Octahedrally Coordinated Mixed Valence Cobalt(II,III) Complex with Thiosemicarbazone Based Ligand”; J. Coord. Chem. 2009, 62, 2600-2609. DOI 10.1080/00958970902915574

41. Dou, D.; Talaty, E.R.; Moore, C.; Bullinger, J.; Eichhorn, D.M.; Groutas, W.C.; “Formation of an Unusual Dimeric Product in the Reaction of a 1,2,5 –Thiadiazolidine 1,1 Dioxide-Derived Thioether with Sulfuryl Chloride”; J. Heterocyclic Chem. 2009, 46, 669 – 673. DOI 10.1002/jhet.136

40. Burns, D.H.; Meece, F.A.; Moore, C.E.; Eichhorn, D.M. “Two similar dibenzo cyclic ethers with dissimilar conformations”; Acta Crystallogr. 2009, C65, o27-o30.

39. Panja, A.; Campana, C.; Leavitt, C.; Van Stipdonk, M.J.; Eichhorn, D.M. “Iron and Cobalt Complexes of 2,6-Diacetylpyridine-bis(R-thiosemicarbazone) (R=H, phenyl) Showing Unprecedented Ligand Deviation from Planarity”; Inorg. Chim. Acta 2009, 362, 1348-1354.

38. Zhao, N.; Bullinger, J.C.; Van Stipdonk, M.J.; Stern, C.L.; Eichhorn, D.M.; “Cyanoscorpionates – Synthesis and Crystallographic Characterization of 1-D Cu(I) Coordination Polymers”; Inorg. Chem. 2008, 47, 5945-5950. DOI: 10.1021/ic8003307

37. Zhao, N.; Van Stipdonk, M.J.; Bauer, C.; Campana, C.; Eichhorn, D.M. “Sandwich Compounds of Cyanotrispyrazolylborates – Complexation-induced Ligand Isomerization”; Inorg. Chem. 2007, 46, 8662-8667. DOI: 10.1021/ic700628b

36. Smucker, B.W.; Van Stipdonk, M.J.; Eichhorn, D.M. “Incorporation of Thiolate Donation Using 2,2'-Dithiodibenzaldehyde: Complexes of a Pentadentate N2S3 Ligand With Relevance to the Active Site of Co Nitrile Hydratase”; J. Inorg. Biochem., 2007, 101, 1537-1542.

35. Zhao, N.; Van Stipdonk, M.J.; Eichhorn, D.M. “Syntheses and Crystal Structures of 3-tert-butyl-4-cyano Pyrazole and its Complexes with Cobalt(II), Manganese(II), and Copper(II)”; Polyhedron, 2007, 26, 2449-2454.

34. Kirgan, R.; Moore, C.; Eichhorn, D.M.; Rillema, D.P. “4-Acetylresorcinol”; Acta Cryst. 2007, E63, o4252.

33. Zhao, N.; Eichhorn, D.M. “Dichlorobis(3,5-dimethylpyrazole)copper(II)” Acta Cryst. 2005, E61, m822-m823.

32. Villegas, J.M.; Stoyanov, S.R.; Moore, C.E.; Eichhorn, D.M.; Rillema, D.P. “fac-Tricarbonyl(2,9-dimethyl-1,10-phenanthroline)(2,6-dimethylphenyl-isocyanide)rhenium(I) hexafluorophosphate” Acta Cryst. 2005, E61, m533-m534.

31. Zhong, J.; Lai, Z.; Groutas, C. S.; Wong, T.; Gan, X.; Alliston, K. R.; Eichhorn, D.; Hoidal, J. R.; Groutas, W. C. “Serendipitous Discovery of an Unexpected Rearrangement Leads to Two New Classes of Potential Protease Inhibitors” Bioorg. Med. Chem. 2004, 12, 6249-6254.

30. Oshin, K.; Landis, A. M.; Smucker, B. W.; Eichhorn, D. M.; Rillema, D. P. “fac-Bipyridyltricarbonyl(pyridine)rhenium(I) trifluoromethanesulfonate” Acta Cryst. 2004, E60, m1126-m1127.

29. Eller, C.; Smucker, B. W.; Kirgan, R.; Eichhorn, D. M.; Rillema, D. P. "5,5'-Dimethyl-2,2'-bipyrazine"; Acta Cryst. 2004, E60, o433-o434.

28. Siemer, C. J.; VanStipdonk, M. J.; Kahol, P. K.; Eichhorn, D. M.; "A Coordination Polymer from a Cyanoscorpionate Complex"; Polyhedron 2004, 23, 235-238.

27. Eichhorn, D. M.; Goswami, N.; "New Synthetic Techniques for the Incorporation of Thiolate Donation in Transition Metal Complexes"; Comm. Inorg. Chem. 2003, 24, 1-13. DOI: 10.1080/02603590390228164

26. Vongtragool, S.; Gorshunov, B.; Dressel, M.; Krzystek, J.; Eichhorn, D. M.; Telser, J.; "Direct Observation of Fine Structure Transitions in a Paramagnetic Nickel(II) Complex Using Far-Infrared Magnetic Spectroscopy: A New Method for Studying High-Spin Transition Metal Complexes"; Inorg Chem. 2003, 42, 1788-1790.

25. Gu, W.; Jacquamet, L.; Patil, D. S.; Wang, H.-X.; Evans, D. J.; Smith, M. C.; Millar, M.; Koch, S.; Eichhorn, D. M.; Latimer, M.; Cramer, S. P.; "Refinement of the Nickel Site Structure in Desulfovibrio gigas Hydrogenase Using Range-extended EXAFS Spectroscopy"; J. Inorg. Biochem. 2003, 93, 41-51.

24. Goswami, N.; Van Stipdonk, M. J.; Eichhorn, D. M.; "Formation of an ethylene-bridged bis(benzisothiazole) dication by oxidative decomplexation of Ni(tsalen) with FeCl3"; Inorg. Chem. Commun. 2003, 6, 86-89.

23. Siemer, C. J.; Meece, F. A.; Armstrong, W. H.; Eichhorn, D. M.; "Iron, Copper, and Cobalt Complexes of Hydrotris(3-phenylpyrazolyl)borate and Dihydrobis(3-phenylpyrazolyl)borate. Synthesis and X-ray Crystallographic Characterization"; Polyhedron 2001, 20, 2637-2646.

22. Siemer, C. J.; Goswami, N.; Van Stipdonk, M. J.; Eichhorn, D. M.; " Dihydrobis(4-cyano-3-phenylpyrazol-1-yl)borate: Homoleptic Mononuclear Cobalt(II) and Copper(II) Complexes With a Cyano-substituted Scorpionate Ligand."; Inorg. Chem., 2001 40, 4081-4084.

21. McCormick, B. J.; Siemer, C.; Afroz, F.; Wasson, J. R.; Eichhorn, D. M.; Scott, B.; Shah, S.; Noffsinger, K.; Kahol, P. K.; "The Copper Acetylenedicarboxylate System" Synthetic Metals, 2001, 120 , 969-970.

20. Shan, B.-Z.; Zhao, Q.; Goswami, N.; Eichhorn, D. M.; Rillema, D. P.; "Structure, NMR, and Other Physical and Photophysical Properties of Ruthenium Complexes Containing the 3,3'-Dicarboxyl-2,2'-Bipyridine Ligand"; Coord. Chem. Rev.; 2001, 211, 117-144.

19. Xue, W.-M.; Goswami, N.; Eichhorn, D. M.; Orizondo, P. L.; Rillema, D. P.; "Synthesis and Luminescence Properties of a Nonsymmetric Ligand-Bridged ReI-ReI Chromophore" Inorg. Chem. 2000, 39, 4460-4467.

18. Burns, D. H.; Chan, H.-K.; Miller, J. D.; Jayne, C. L; Eichhorn, D. M. " Synthesis, Modification, and Characterization of a Family of Homologs of exo-Calix[4]arene: exo-[n.m.n.m]Metacyclophanes, n,m≥3"; J. Org. Chem., 2000, 65, 5185-5196.

17. Goswami, N.; Eichhorn, D. M.; "Incorporation of Thiolate Donation Using 2,2'-Dithiodibenzaldehyde: Synthesis of Ni, Fe, and Cu Complexes. Crystal Structures of [M(tsalen)] (tsalen = N,N'-Ethylenebis(thiosalicylidene)imine); M = Cu, Ni) Showing a Tetrahedral Distortion of Cu(tsalen)"Inorg. Chim. Acta , 2000,303, 272-277.

16. Depriest, J.; Zheng, G. Y.; Goswami, N.; Eichhorn, D. M.; Woods, C.; Rillema, D. P.; "Structure, Physical and Photophysical Properties of Platinum(II) Complexes Containing Bidentate Aromatic and Bis(diphenylphosphino)methane as Ligands"; Inorg. Chem. 2000, 39, 1955-1963.

15. Deviprasad, G. R.; Eichhorn, D. M.; D'Souza, F. "Crystal Structure and Intermolecular Coordination Behavior of a Porphyrin Bearing Hydroquinone Receptor, meso-Mono(hydroquinonyl)triphenylporphyrinatozinc" J. Chem. Crystallogr. 1999 29, 849-853*

14. Goswami, N.; Eichhorn, D. M.; "A New Method for Incorporating Thiolate Donors into a Metal Coordination Sphere. Synthesis and Crystal Structures of the First Nickel Complexes of an N3S Ligand" Inorg. Chem. 1999, 36, 4329-4333.

13. Wang, Y.; Eichhorn, D. M.; Goswami, N.; Zhao, Q.; Rillema, D. P.; "Crystal Structure and Physical Properties of a Ruthenium(II) Bipyridine Complex" J. Chem. Crystallog. 1999, 29, 277-281.

12. Huyett, J.E.; Choudhury, S.B.; Eichhorn, D. M.; Bryngelson, P.A.; Maroney, M.J.; Hoffman, B.M.; "Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel]-: An Investigation into the Ligand Electronic Structure" Inorg. Chem. 1998, 37, 1361-1367.

11. Andersen, K.; Andersen, M.; Anderson, O. P.; Baum, S.; Baumann, T. G.; Beall, L. S.; Broderick, W. E.; Cook, A. S.; Eichhorn, D. M.; Goldberg, D.; Hope, H.; Jarrell, W.; Lange, S. J.; McCubbin, Q. J.; Mani, N. S.; Miller, T.; Garrido Montalban, A.; Rodriquez-Morgade, M. S.; Lee, S.; Nie, H.; Olmstead, M. M.; Sabat, M.; Sibert, J. W.; Stern, C.; White, A. J. P.; Williams, D. B. G.; Williams, D. J.; Barrett, A. G. M.; Hoffman, B. M.; “Star Porphyrazines and Related Multimetallic Macrocycles” J. Heterocyclic Chem. 1998, 35, 1013-1042.

10. Eichhorn, D. M.; Yang, S.; Jarrell, W.; Baumann, T.; Beall, L.S.; White, A.J.P.; Williams, D.J.; Barrett, A.G.M.; Hoffman, B.M.; “[60]Fullerene and TCNQ Donor-Acceptor Crystals of Octakis(dimethylamino)porphyrazine” J. Chem. Soc., Chem. Commun.1995, 1703-1704.

9. Broderick, W.E.; Eichhorn, D. M.; Liu, X.; Toscano, P.M.; Owen, S.; Hoffman, B.M.; "Three Phases of [Fe(C5Me5)2]+[TCNQ]-: Ferromagnetism in a New Structural Phase" J. Am. Chem. Soc. 1995, 117, 3641-3642.

8. Broderick, W.E.; Eichhorn, D. M.; Liu, X., Owens, S.; Toscano, P.M.; Hoffman, B.M.; "Ferromagnetism in a New Structural Phase of [Fe(C5Me5)2][TCNQ]" Mol. Cryst. Liq. Cryst. 1995, 273, 17-20.

7. Eichhorn, D. M.; Telser, J.; Stern, C.L.; Hoffman, B.M.; "Influence of Zero-Field Splitting and State Mixing on Ferromagnetic Exchange in the Integrated-Stack Charge-Transfer Salt [Cp*2Fe][Co(HMPA-B)]" Inorg. Chem. 1994, 33, 3533-3537.

6. Eichhorn, D. M.; Skee, D.C.; Broderick, W.E.; Hoffman, B.M.; "Ferromagnetism in Decamethylchromocenium tetracyanoethylenide" Inorg. Chem. 1993, 32, 491-492.

5. Eichhorn, D. M., Armstrong, W.H.; "A Remarkably Stable Mononuclear Manganese(III) Hydroxide Complex: [L1MnIII(OH)] (L1=bis(2-hydroxy, 5-nitrobenzyliminopropyl)¬methylamine)" J. Chem. Soc., Chem. Commun. 1992, 85-87.

4. Cramer, S.P.; deGroot, F.M.F.; Ma, Y.; Chen, C.T.; Sette, F.; Kipke, C.A.; Eichhorn, D. M.; Chan, M.K.; Armstrong, W.H.; Fuggle, J.C. "Ligand Field Strengths and Oxidation States from Manganese L-Edge Spectroscopy" J. Am. Chem. Soc. 1991, 113, 7937-7940.

3. Chambron, J.-C.; Eichhorn, D. M.; Franczyk, T.S.; Stearns, D.M. "Structure of [Hydro(trispyrazolylborato)-triphenylphosphinoiodomethyl] Rhodium(III)"Acta Crystallogr., 1991, C47, 1732-1734.

2. Low, D.W.; Eichhorn, D. M.; Draganescu, A.; Armstrong, W.H. "Structure and Properties of [Mn9O7(O2CC6H5)13py)2]: A Novel Nonanuclear Mn(III) Oxo-Carboxylate Species Synthesized by Employing an Oxygen Atom Transfer Agent" Inorg. Chem., 1991, 30, 877-878.

1. Eichhorn, D. M.; Armstrong, W.H. "M{(Hydrotris(3-phenyl-pyrazolyl)borate}2: Sterically Encumbered Iron(II) and Manganese(II) Complexes " Inorg. Chem. 1990, 29, 3607-3612.